Pharmacological and Pharmaceutical Sciences
Novikov SA, Lu Y, Zhang W, Halasyamani PS, Hariyani S, Brgoch J, Klepov VV, Zur Loye HC, Mozharivskyj Y
Phosphorescence in Mn4+-Doped R+/R2+ Germanates (R+ = Na+ or K+, R2+ = Sr2+). Inorg Chem. 2022 Jun 20; 61(24):9364-9374.
Phosphorescence in Mn4+-Doped R+/R2+ Germanates (R+ = Na+ or K+, R2+ = Sr2+).
Dalton transactions (Cambridge, England : 2003)
Synthesis and large crystal growth of a family of mixed-anionic methanesulfonate salts by anionic site-substitution: Na5(SO3CH3)4(X) (X = BF4-, ClO4-, PF6-, I-). Dalton Trans. 2025 Mar 25; 54(13):5301-5310.
Synthesis and large crystal growth of a family of mixed-anionic methanesulfonate salts by anionic site-substitution: Na5(SO3CH3)4(X) (X = BF4-, ClO4-, PF6-, I-).
Synthesis and Large Crystal Growth of a Noncentrosymmetric Sodium Methylsulfanetriol Borate Lewis-Adduct: Na(S(OH)3CH3)(BO3). Inorg Chem. 2024 Sep 16; 63(37):17208-17214.
Synthesis and Large Crystal Growth of a Noncentrosymmetric Sodium Methylsulfanetriol Borate Lewis-Adduct: Na(S(OH)3CH3)(BO3).
Wang S, Zhang Y, Halasyamani PS, Mitzi DB
Chirality and Solvent Coassist the Structural Evolution of Hybrid Manganese Chlorides with Second-Harmonic-Generation Response. Inorg Chem. 2024 Sep 02; 63(35):16121-16127.
Chirality and Solvent Coassist the Structural Evolution of Hybrid Manganese Chlorides with Second-Harmonic-Generation Response.
Wang J, Zhu M, Chu Y, Tian J, Liu L, Zhang B, Halasyamani PS
Small (Weinheim an der Bergstrasse, Germany)
Rational Design of the Alkali Metal Sn-Based Mixed Halides with Large Birefringence and Wide Transparent Range. Small. 2024 Apr; 20(17):e2308884.
Rational Design of the Alkali Metal Sn-Based Mixed Halides with Large Birefringence and Wide Transparent Range.
Mallick S, Orlandi F, Manuel P, Zhang W, Halasyamani PS, Hayward MA
Chemistry of materials : a publication of the American Chemical Society
MnCaTa2O7-A Magnetically Ordered Polar Phase Prepared via Cation Exchange. Chem Mater. 2023 Sep 26; 35(18):7839-7846.
MnCaTa2O7-A Magnetically Ordered Polar Phase Prepared via Cation Exchange.
Wang Y, Nisbet ML, Kamp KR, Hiralal E, Gautier R, Halasyamani PS, Poeppelmeier KR
Journal of the American Chemical Society
Beyond p-p Stacking: Understanding Inversion Symmetry Breaking in Crystalline Racemates. J Am Chem Soc. 2023 Aug 02; 145(30):16879-16888.
Beyond p-p Stacking: Understanding Inversion Symmetry Breaking in Crystalline Racemates.
King AA, Breton LS, Morrison G, Smith MD, Liang M, Halasyamani PS, Zur Loye HC
Crystal Structures and Property Measurements of Rare Earth Magnesium Thiosilicates Synthesized via Flux Crystal Growth Utilizing the Boron Chalcogen Mixture (BCM) Method. Inorg Chem. 2023 May 15; 62(19):7446-7452.
Crystal Structures and Property Measurements of Rare Earth Magnesium Thiosilicates Synthesized via Flux Crystal Growth Utilizing the Boron Chalcogen Mixture (BCM) Method.
Cassingham MA, Goh YG, McClure ET, Hodgkins TL, Zhang W, Liang M, Dawlaty JM, Djurovich PI, Haiges R, Halasyamani PS, Savory CN, Thompson ME, Melot BC
Polarizable Anionic Sublattices Can Screen Molecular Dipoles in Noncentrosymmetric Inorganic-Organic Hybrids. ACS Appl Mater Interfaces. 2023 Apr 12; 15(14):18006-18011.
Polarizable Anionic Sublattices Can Screen Molecular Dipoles in Noncentrosymmetric Inorganic-Organic Hybrids.
Ding F, Griffith KJ, Zhang W, Cui S, Zhang C, Wang Y, Kamp K, Yu H, Halasyamani PS, Yang Z, Pan S, Poeppelmeier KR
NaRb6(B4O5(OH)4)3(BO2) Featuring Noncentrosymmetry, Chirality, and the Linear Anionic Group BO2. J Am Chem Soc. 2023 Mar 08; 145(9):4928-4933.
NaRb6(B4O5(OH)4)3(BO2) Featuring Noncentrosymmetry, Chirality, and the Linear Anionic Group BO2.
Liang ML, Lacroix M, Tao C, Waters MJ, Rondinelli JM, Halasyamani PS
Noncentrosymmetric ?-Cs2I4O11 Obtained from IO4 Polyhedral Rearrangements in the Centrosymmetric ?-Phase. Inorg Chem. 2023 Feb 13; 62(6):2942-2950.
Noncentrosymmetric ?-Cs2I4O11 Obtained from IO4 Polyhedral Rearrangements in the Centrosymmetric ?-Phase.
Scott EAS, Mitoudi Vagourdi E, Johnsson M, Cascos V, John F, Pickup D, Chadwick AV, Djani H, Bousquet E, Zhang W, Halasyamani PS, McCabe EE
Bi2CoO2F4-A Polar, Ferrimagnetic Aurivillius Oxide-Fluoride. Chem Mater. 2022 Nov 08; 34(21):9775-9785.
Bi2CoO2F4-A Polar, Ferrimagnetic Aurivillius Oxide-Fluoride.
Breton LS, Morrison G, Lacroix MR, Halasyamani PS, Zur Loye HC
Chemical communications (Cambridge, England)
Lanthanide thioborates, an emerging class of nonlinear optical materials, efficiently synthesized using the boron-chalcogen mixture method. Chem Commun (Camb). 2022 Jul 14; 58(57):7992-7995.
Lanthanide thioborates, an emerging class of nonlinear optical materials, efficiently synthesized using the boron-chalcogen mixture method.
Fuller CA, Murrell JI, Blom DA, Vogt T, Zhang W, Halasyamani PS, Evans IR, Evans JSO
Oxide Ion Conductivity, Proton Conductivity, and Phase Transitions in Perovskite-Derived Ba3-x Sr x YGa2O7.5 0 = x = 3 Materials. Chem Mater. 2022 Apr 12; 34(7):3185-3196.
Oxide Ion Conductivity, Proton Conductivity, and Phase Transitions in Perovskite-Derived Ba3-x Sr x YGa2O7.5 0 = x = 3 Materials.
Han C, Bradford AJ, McNulty JA, Zhang W, Halasyamani PS, Slawin AMZ, Morrison FD, Lee SL, Lightfoot P
Polarity and Ferromagnetism in Two-Dimensional Hybrid Copper Perovskites with Chlorinated Aromatic Spacers. Chem Mater. 2022 Mar 08; 34(5):2458-2467.
Polarity and Ferromagnetism in Two-Dimensional Hybrid Copper Perovskites with Chlorinated Aromatic Spacers.
Mallick S, Zhang W, Batuk M, Gibbs AS, Hadermann J, Halasyamani PS, Hayward MA
The crystal and defect structures of polar KBiNb2O7. Dalton Trans. 2022 Feb 01; 51(5):1866-1873.
The crystal and defect structures of polar KBiNb2O7.
Ding F, Charles N, Harada JK, Malliakas CD, Zhang C, Dos Reis R, Griffith KJ, Nisbet ML, Zhang W, Halasyamani PS, Dravid VP, Rondinelli JM, Poeppelmeier KR
Perovskite-like K3TiOF5 Exhibits (3 + 1)-Dimensional Commensurate Structure Induced by Octahedrally Coordinated Potassium Ions. J Am Chem Soc. 2021 Nov 17; 143(45):18907-18916.
Perovskite-like K3TiOF5 Exhibits (3 + 1)-Dimensional Commensurate Structure Induced by Octahedrally Coordinated Potassium Ions.
Mallick S, Khalsa G, Kaaret JZ, Zhang W, Batuk M, Gibbs AS, Hadermann J, Halasyamani PS, Benedek NA, Hayward MA
The influence of the 6s2 configuration of Bi3+ on the structures of A'BiNb2O7 (A' = Rb, Na, Li) layered perovskite oxides. Dalton Trans. 2021 Nov 02; 50(42):15359-15369.
The influence of the 6s2 configuration of Bi3+ on the structures of A'BiNb2O7 (A' = Rb, Na, Li) layered perovskite oxides.
Ayer GB, Smith MD, Jacobsohn LG, Morrison G, Tisdale HB, Breton LS, Zhang W, Halasyamani PS, Zur Loye HC
Synthesis of Hydrated Ternary Lanthanide-Containing Chlorides Exhibiting X-ray Scintillation and Luminescence. Inorg Chem. 2021 Oct 18; 60(20):15371-15382.
Synthesis of Hydrated Ternary Lanthanide-Containing Chlorides Exhibiting X-ray Scintillation and Luminescence.
Zhu T, Orlandi F, Manuel P, Gibbs AS, Zhang W, Halasyamani PS, Hayward MA
Directed synthesis of a hybrid improper magnetoelectric multiferroic material. Nat Commun. 2021 Aug 16; 12(1):4945.
Directed synthesis of a hybrid improper magnetoelectric multiferroic material.
Sandineni P, Yaghoobnejad Asl H, Zhang W, Halasyamani PS, Ghosh K, Choudhury A
Interplay between Oxo and Fluoro in Vanadium Oxyfluorides for Centrosymmetric and Non-Centrosymmetric Structure Formation. Molecules. 2021 Jan 24; 26(3).
Interplay between Oxo and Fluoro in Vanadium Oxyfluorides for Centrosymmetric and Non-Centrosymmetric Structure Formation.
Cascos VA, Roberts-Watts J, Skingle C, Levin I, Zhang W, Halasyamani PS, Stennett MC, Hyatt NC, Bousquet E, McCabe EE
Tuning between Proper and Hybrid-Improper Mechanisms for Polar Behavior in CsLn2Ti2NbO10 Dion-Jacobson Phases. Chem Mater. 2020 Oct 13; 32(19):8700-8712.
Tuning between Proper and Hybrid-Improper Mechanisms for Polar Behavior in CsLn2Ti2NbO10 Dion-Jacobson Phases.
Menezes LT, Assoud A, Zhang W, Halasyamani PS, Kleinke H
Effect of Pb Substitution in Sr2-xPbxGeSe4 on Crystal Structures and Nonlinear Optical Properties Predicted by DFT Calculations. Inorg Chem. 2020 Oct 19; 59(20):15028-15035.
Effect of Pb Substitution in Sr2-xPbxGeSe4 on Crystal Structures and Nonlinear Optical Properties Predicted by DFT Calculations.
Usman M, Kocevski V, Smith MD, Morrison G, Zhang W, Besmann T, Halasyamani PS, Zur Loye HC
Polymorphism and Molten Nitrate Salt-Assisted Single Crystal to Single Crystal Ion Exchange in the Cesium Ferrogermanate Zeotype: CsFeGeO4. Inorg Chem. 2020 Jul 20; 59(14):9699-9709.
Polymorphism and Molten Nitrate Salt-Assisted Single Crystal to Single Crystal Ion Exchange in the Cesium Ferrogermanate Zeotype: CsFeGeO4.
Mitoudi Vagourdi E, Zhang W, Denisova K, Lemmens P, Halasyamani PS, Johnsson M
Synthesis and Characterization of Two New Second Harmonic Generation Active Iodates: K3Sc(IO3)6 and KSc(IO3)3Cl. ACS Omega. 2020 Mar 17; 5(10):5235-5240.
Synthesis and Characterization of Two New Second Harmonic Generation Active Iodates: K3Sc(IO3)6 and KSc(IO3)3Cl.
Hancock JC, Nisbet ML, Zhang W, Halasyamani PS, Poeppelmeier KR
Periodic Tendril Perversion and Helices in the AMoO2F3 (A = K, Rb, NH4, Tl) Family. J Am Chem Soc. 2020 04 01; 142(13):6375-6380.
Periodic Tendril Perversion and Helices in the AMoO2F3 (A = K, Rb, NH4, Tl) Family.
Wu H, Zhang B, Yu H, Hu Z, Wang J, Wu Y, Halasyamani PS
Angewandte Chemie (International ed. in English)
Designing Silicates as Deep-UV Nonlinear Optical (NLO) Materials using Edge-Sharing Tetrahedra. Angew Chem Int Ed Engl. 2020 Jun 02; 59(23):8922-8926.
Designing Silicates as Deep-UV Nonlinear Optical (NLO) Materials using Edge-Sharing Tetrahedra.
Zhou J, Wu H, Yu H, Jiang S, Hu Z, Wang J, Wu Y, Halasyamani PS
BaF2TeF2(OH)2: A UV Nonlinear Optical Fluorotellurite Material Designed by Band-Gap Engineering. J Am Chem Soc. 2020 Mar 11; 142(10):4616-4620.
BaF2TeF2(OH)2: A UV Nonlinear Optical Fluorotellurite Material Designed by Band-Gap Engineering.
Ding F, Zhang W, Nisbet ML, Zhang W, Halasyamani PS, Yang Z, Pan S, Poeppelmeier KR
NaRb3B6O9(OH)3(HCO3): A Borate-Bicarbonate Nonlinear Optical Material. Inorg Chem. 2020 Jan 06; 59(1):759-766.
NaRb3B6O9(OH)3(HCO3): A Borate-Bicarbonate Nonlinear Optical Material.
Jafarzadeh P, Menezes LT, Cui M, Assoud A, Zhang W, Halasyamani PS, Kleinke H
BaCuSiTe3: A Noncentrosymmetric Semiconductor with CuTe4 Tetrahedra and Ethane-like Si2Te6 Units. Inorg Chem. 2019 Sep 03; 58(17):11656-11663.
BaCuSiTe3: A Noncentrosymmetric Semiconductor with CuTe4 Tetrahedra and Ethane-like Si2Te6 Units.
McNulty JA, Tran TT, Halasyamani PS, McCartan SJ, MacLaren I, Gibbs AS, Lim FJY, Turner PW, Gregg JM, Lightfoot P, Morrison FD
Advanced materials (Deerfield Beach, Fla.)
An Electronically Driven Improper Ferroelectric: Tungsten Bronzes as Microstructural Analogs for the Hexagonal Manganites. Adv Mater. 2019 Oct; 31(40):e1903620.
An Electronically Driven Improper Ferroelectric: Tungsten Bronzes as Microstructural Analogs for the Hexagonal Manganites.
Usman M, Smith MD, Morrison G, Klepov VV, Zhang W, Halasyamani PS, Zur Loye HC
Molten Alkali Halide Flux Growth of an Extensive Family of Noncentrosymmetric Rare Earth Sulfides: Structure and Magnetic and Optical (SHG) Properties. Inorg Chem. 2019 Jul 01; 58(13):8541-8550.
Molten Alkali Halide Flux Growth of an Extensive Family of Noncentrosymmetric Rare Earth Sulfides: Structure and Magnetic and Optical (SHG) Properties.
Bhim A, Zhang W, Halasyamani PS, Gopalakrishnan J, Natarajan S
New Members of SHG Active Dugganite Family, A3BC3D2O14 (A = Ba, Pb; B = Te, Sb; C = Al, Ga, Fe, Zn; D = Si, Ge, P, V): Synthesis, Structure, and Materials Properties. Inorg Chem. 2019 Jul 01; 58(13):8560-8569.
New Members of SHG Active Dugganite Family, A3BC3D2O14 (A = Ba, Pb; B = Te, Sb; C = Al, Ga, Fe, Zn; D = Si, Ge, P, V): Synthesis, Structure, and Materials Properties.
Li Y, Zhang D, Liu L, Zhang W, Zhang J, Cong Y, Li X, Halasyamani PS
Cs2CdV2O6Cl2 and Cs3CdV4O12Br: two new non-centrosymmetric oxyhalides containing d0 and d10 cations and exhibiting second harmonic generation activity. Dalton Trans. 2019 Jul 16; 48(28):10642-10651.
Cs2CdV2O6Cl2 and Cs3CdV4O12Br: two new non-centrosymmetric oxyhalides containing d0 and d10 cations and exhibiting second harmonic generation activity.
Liu H, Zhang W, Halasyamani PS, Stokes HT, Campbell BJ, Evans JSO, Evans IR
Understanding the Behavior of the Above-Room-Temperature Molecular Ferroelectric 5,6-Dichloro-2-methylbenzimidazole Using Symmetry Adapted Distortion Mode Analysis. J Am Chem Soc. 2018 Oct 17; 140(41):13441-13448.
Understanding the Behavior of the Above-Room-Temperature Molecular Ferroelectric 5,6-Dichloro-2-methylbenzimidazole Using Symmetry Adapted Distortion Mode Analysis.
Ding F, Nisbet ML, Zhang W, Halasyamani PS, Chai L, Poeppelmeier KR
Why Some Noncentrosymmetric Borates Do Not Make Good Nonlinear Optical Materials: A Case Study with K3B5O8(OH)2. Inorg Chem. 2018 Sep 17; 57(18):11801-11808.
Why Some Noncentrosymmetric Borates Do Not Make Good Nonlinear Optical Materials: A Case Study with K3B5O8(OH)2.
The must-have and nice-to-have experimental and computational requirements for functional frequency doubling deep-UV crystals. Nat Commun. 2018 07 30; 9(1):2972.
The must-have and nice-to-have experimental and computational requirements for functional frequency doubling deep-UV crystals.
Ding F, Nisbet ML, Yu H, Zhang W, Chai L, Halasyamani PS, Poeppelmeier KR
Syntheses, Structures, and Properties of Non-Centrosymmetric Quaternary Tellurates Bi MTeO6 ( M = Al, Ga). Inorg Chem. 2018 Jul 02; 57(13):7950-7956.
Syntheses, Structures, and Properties of Non-Centrosymmetric Quaternary Tellurates Bi MTeO6 ( M = Al, Ga).
Ba4B8TeO19: A UV Nonlinear Optical Material. Inorg Chem. 2018 Apr 16; 57(8):4771-4776.
Ba4B8TeO19: A UV Nonlinear Optical Material.
Yu H, Koocher NZ, Rondinelli JM, Halasyamani PS
Pb2 BO3 I: A Borate Iodide with the Largest Second-Harmonic Generation (SHG) Response in the KBe2 BO3 F2 (KBBF) Family of Nonlinear Optical (NLO) Materials. Angew Chem Int Ed Engl. 2018 05 22; 57(21):6100-6103.
Pb2 BO3 I: A Borate Iodide with the Largest Second-Harmonic Generation (SHG) Response in the KBe2 BO3 F2 (KBBF) Family of Nonlinear Optical (NLO) Materials.
Viewpoint: Inorganic Materials for UV and Deep-UV Nonlinear-Optical Applications. Inorg Chem. 2017 Oct 16; 56(20):12077-12085.
Viewpoint: Inorganic Materials for UV and Deep-UV Nonlinear-Optical Applications.
Zhang R, Gibbs AS, Zhang W, Halasyamani PS, Hayward MA
Structural Modification of the Cation-Ordered Ruddlesden-Popper Phase YSr2Mn2O7 by Cation Exchange and Anion Insertion. Inorg Chem. 2017 Aug 21; 56(16):9988-9995.
Structural Modification of the Cation-Ordered Ruddlesden-Popper Phase YSr2Mn2O7 by Cation Exchange and Anion Insertion.
Deep-Ultraviolet Nonlinear-Optical Material K3Sr3Li2Al4B6O20F: Addressing the Structural Instability Problem in KBe2BO3F2. Inorg Chem. 2017 Aug 07; 56(15):8755-8758.
Deep-Ultraviolet Nonlinear-Optical Material K3Sr3Li2Al4B6O20F: Addressing the Structural Instability Problem in KBe2BO3F2.
Abeysinghe D, Smith MD, Yeon J, Tran TT, Paria Sena R, Hadermann J, Halasyamani PS, Zur Loye HC
Crystal Growth and Structure Analysis of Ce18W10O57: A Complex Oxide Containing Tungsten in an Unusual Trigonal Prismatic Coordination Environment. Inorg Chem. 2017 Mar 06; 56(5):2566-2575.
Crystal Growth and Structure Analysis of Ce18W10O57: A Complex Oxide Containing Tungsten in an Unusual Trigonal Prismatic Coordination Environment.
Tran TT, Koocher NZ, Rondinelli JM, Halasyamani PS
Beryllium-Free ?-Rb2 Al2 B2 O7 as a Possible Deep-Ultraviolet Nonlinear Optical Material Replacement for KBe2 BO3 F2. Angew Chem Int Ed Engl. 2017 03 06; 56(11):2969-2973.
Beryllium-Free ?-Rb2 Al2 B2 O7 as a Possible Deep-Ultraviolet Nonlinear Optical Material Replacement for KBe2 BO3 F2.
Tran TT, Young J, Rondinelli JM, Halasyamani PS
Mixed-Metal Carbonate Fluorides as Deep-Ultraviolet Nonlinear Optical Materials. J Am Chem Soc. 2017 01 25; 139(3):1285-1295.
Mixed-Metal Carbonate Fluorides as Deep-Ultraviolet Nonlinear Optical Materials.
Geng L, Li Q, Lu H, Dai K, Halasyamani PS
Sb-Based antiferromagnetic oxychlorides: MSb2O3(OH)Cl (M = Mn, Fe, Co) with 2D spin-dimer structures. Dalton Trans. 2016 Nov 15; 45(45):18183-18189.
Sb-Based antiferromagnetic oxychlorides: MSb2O3(OH)Cl (M = Mn, Fe, Co) with 2D spin-dimer structures.
Zhang R, Abbett BM, Read G, Lang F, Lancaster T, Tran TT, Halasyamani PS, Blundell SJ, Benedek NA, Hayward MA
La2SrCr2O7: Controlling the Tilting Distortions of n = 2 Ruddlesden-Popper Phases through A-Site Cation Order. Inorg Chem. 2016 Sep 06; 55(17):8951-60.
La2SrCr2O7: Controlling the Tilting Distortions of n = 2 Ruddlesden-Popper Phases through A-Site Cation Order.
Yu H, Young J, Wu H, Zhang W, Rondinelli JM, Halasyamani PS
Electronic, Crystal Chemistry, and Nonlinear Optical Property Relationships in the Dugganite A3B3CD2O14 Family. J Am Chem Soc. 2016 Apr 13; 138(14):4984-9.
Electronic, Crystal Chemistry, and Nonlinear Optical Property Relationships in the Dugganite A3B3CD2O14 Family.
Morrison G, Tran TT, Halasyamani PS, zur Loye HC
K8(K5F)U6Si8O40: An Intergrowth Uranyl Silicate. Inorg Chem. 2016 Apr 04; 55(7):3215-7.
K8(K5F)U6Si8O40: An Intergrowth Uranyl Silicate.
Yu H, Zhang W, Young J, Rondinelli JM, Halasyamani PS
Bidenticity-Enhanced Second Harmonic Generation from Pb Chelation in Pb3Mg3TeP2O14. J Am Chem Soc. 2016 Jan 13; 138(1):88-91.
Bidenticity-Enhanced Second Harmonic Generation from Pb Chelation in Pb3Mg3TeP2O14.
Design and Synthesis of the Beryllium-Free Deep-Ultraviolet Nonlinear Optical Material Ba3(ZnB5O10)PO4. Adv Mater. 2015 Dec 02; 27(45):7380-5.
Design and Synthesis of the Beryllium-Free Deep-Ultraviolet Nonlinear Optical Material Ba3(ZnB5O10)PO4.
Tran TT, He J, Rondinelli JM, Halasyamani PS
RbMgCO3F: A New Beryllium-Free Deep-Ultraviolet Nonlinear Optical Material. J Am Chem Soc. 2015 Aug 26; 137(33):10504-7.
RbMgCO3F: A New Beryllium-Free Deep-Ultraviolet Nonlinear Optical Material.
Kim SW, Zhang R, Halasyamani PS, Hayward MA
K4Fe3F12: An Fe(2+)/Fe(3+) Charge-Ordered, Ferrimagnetic Fluoride with a Cation-Deficient, Layered Perovskite Structure. Inorg Chem. 2015 Jul 06; 54(13):6647-52.
K4Fe3F12: An Fe(2+)/Fe(3+) Charge-Ordered, Ferrimagnetic Fluoride with a Cation-Deficient, Layered Perovskite Structure.
Cortese AJ, Wilkins B, Smith MD, Yeon J, Morrison G, Tran TT, Halasyamani PS, zur Loye HC
Crystal growth of four oxovanadium(IV) tartrates prepared via a mild two-step hydrothermal method: observation of spin-dimer behavior and second harmonic generation. Inorg Chem. 2015 Apr 20; 54(8):4011-20.
Crystal growth of four oxovanadium(IV) tartrates prepared via a mild two-step hydrothermal method: observation of spin-dimer behavior and second harmonic generation.
Role of acentric displacements on the crystal structure and second-harmonic generating properties of RbPbCO3F and CsPbCO3F. Inorg Chem. 2014 Jun 16; 53(12):6241-51.
Role of acentric displacements on the crystal structure and second-harmonic generating properties of RbPbCO3F and CsPbCO3F.
Synthesis, structure, and characterization of two new polar sodium tungsten selenites: Na2(WO3)3(SeO3)?2H2O and Na6(W6O19)(SeO3)2. Inorg Chem. 2013 Mar 04; 52(5):2637-47.
Synthesis, structure, and characterization of two new polar sodium tungsten selenites: Na2(WO3)3(SeO3)?2H2O and Na6(W6O19)(SeO3)2.
New fluoride carbonates: centrosymmetric KPb2(CO3)2F and noncentrosymmetric K2.70Pb5.15(CO3)5F3. Inorg Chem. 2013 Mar 04; 52(5):2466-73.
New fluoride carbonates: centrosymmetric KPb2(CO3)2F and noncentrosymmetric K2.70Pb5.15(CO3)5F3.
Dolgos MR, Adem U, Manjon-Sanz A, Wan X, Comyn TP, Stevenson T, Bennett J, Bell AJ, Tran TT, Halasyamani PS, Claridge JB, Rosseinsky MJ
Angewandte Chemie (Weinheim an der Bergstrasse, Germany)
Perovskite B-Site Compositional Control of [110]p Polar Displacement Coupling in an Ambient-Pressure-Stable Bismuth-based Ferroelectric. Angew Chem Weinheim Bergstr Ger. 2012 Oct 22; 124(43):10928-10933.
Perovskite B-Site Compositional Control of [110]p Polar Displacement Coupling in an Ambient-Pressure-Stable Bismuth-based Ferroelectric.
Synthesis, structure, and characterization of new Li+-d0-lone-pair-oxides: noncentrosymmetric polar Li6(Mo2O5)3(SeO3)6 and centrosymmetric Li2(MO3)(TeO3) (M = Mo6+ or W6+). Inorg Chem. 2012 Sep 03; 51(17):9529-38.
Synthesis, structure, and characterization of new Li+-d0-lone-pair-oxides: noncentrosymmetric polar Li6(Mo2O5)3(SeO3)6 and centrosymmetric Li2(MO3)(TeO3) (M = Mo6+ or W6+).
Yeon J, Kim SH, Nguyen SD, Lee H, Halasyamani PS
Two new noncentrosymmetric (NCS) polar oxides: syntheses, characterization, and structure-property relationships in BaMTe2O7 (M = Mg2+ or Zn2+). Inorg Chem. 2012 Feb 20; 51(4):2662-8.
Two new noncentrosymmetric (NCS) polar oxides: syntheses, characterization, and structure-property relationships in BaMTe2O7 (M = Mg2+ or Zn2+).
New vanadium selenites: centrosymmetric Ca2(VO2)2(SeO3)3(H2O)2, Sr2(VO2)2(SeO3)3, and Ba(V2O5)(SeO3), and noncentrosymmetric and polar A4(VO2)2(SeO3)4(Se2O5) (A = Sr2+ or Pb2+). Inorg Chem. 2012 Jan 02; 51(1):609-19.
New vanadium selenites: centrosymmetric Ca2(VO2)2(SeO3)3(H2O)2, Sr2(VO2)2(SeO3)3, and Ba(V2O5)(SeO3), and noncentrosymmetric and polar A4(VO2)2(SeO3)4(Se2O5) (A = Sr2+ or Pb2+).
Yeon J, Kim SH, Hayward MA, Halasyamani PS
"A" cation polarity control in ACuTe2O7 (A = Sr2+, Ba2+, or Pb2+). Inorg Chem. 2011 Sep 05; 50(17):8663-70.
"A" cation polarity control in ACuTe2O7 (A = Sr2+, Ba2+, or Pb2+).
Nguyen SD, Yeon J, Kim SH, Halasyamani PS
BiO(IO3): a new polar iodate that exhibits an aurivillius-type (Bi2O2)2+ layer and a large SHG response. J Am Chem Soc. 2011 Aug 17; 133(32):12422-5.
BiO(IO3): a new polar iodate that exhibits an aurivillius-type (Bi2O2)2+ layer and a large SHG response.
Synthesis, characterization, and structure-property relationships in two new polar oxides: Zn2(MoO4)(SeO3) and Zn2(MoO4)(TeO3). Inorg Chem. 2011 Jun 06; 50(11):5215-22.
Synthesis, characterization, and structure-property relationships in two new polar oxides: Zn2(MoO4)(SeO3) and Zn2(MoO4)(TeO3).
Selective pure-phase synthesis of the multiferroic BaMF(4) (M = Mg, Mn, Co, Ni, and Zn) family. J Am Chem Soc. 2010 Dec 22; 132(50):17684-5.
Selective pure-phase synthesis of the multiferroic BaMF(4) (M = Mg, Mn, Co, Ni, and Zn) family.
A3V5O14 (A = K+, Rb+, or Tl+), new polar oxides with a tetragonal tungsten bronze related structural topology: synthesis, structure, and functional properties. Inorg Chem. 2010 Aug 02; 49(15):6986-93.
A3V5O14 (A = K+, Rb+, or Tl+), new polar oxides with a tetragonal tungsten bronze related structural topology: synthesis, structure, and functional properties.
Polar or nonpolar? A+ cation polarity control in A2Ti(IO3)6 (A = Li, Na, K, Rb, Cs, Tl). J Am Chem Soc. 2009 May 20; 131(19):6865-73.
Polar or nonpolar? A+ cation polarity control in A2Ti(IO3)6 (A = Li, Na, K, Rb, Cs, Tl).
Alignment of lone pairs in a new polar material: synthesis, characterization, and functional properties of Li2Ti(IO3)6. J Am Chem Soc. 2009 Feb 25; 131(7):2426-7.
Alignment of lone pairs in a new polar material: synthesis, characterization, and functional properties of Li2Ti(IO3)6.
Chang HY, Sivakumar T, Ok KM, Halasyamani PS
Polar hexagonal tungsten bronze-type oxides: KNbW2O9, RbNbW2O9, and KTaW2O9. Inorg Chem. 2008 Oct 06; 47(19):8511-7.
Polar hexagonal tungsten bronze-type oxides: KNbW2O9, RbNbW2O9, and KTaW2O9.
Preface: Overview of the forum on functional inorganic materials. Inorg Chem. 2008 Oct 06; 47(19):8427-8.
Preface: Overview of the forum on functional inorganic materials.
Chang HY, Ok KM, Kim JH, Halasyamani PS, Stoltzfus M, Woodward P
Synthesis, structure, characterization, and calculations of two new Sn2+ -W6+-oxides, Sn2WO5 and Sn3WO6. Inorg Chem. 2007 Aug 20; 46(17):7005-11.
Synthesis, structure, characterization, and calculations of two new Sn2+ -W6+-oxides, Sn2WO5 and Sn3WO6.
Bulk characterization methods for non-centrosymmetric materials: second-harmonic generation, piezoelectricity, pyroelectricity, and ferroelectricity. Chem Soc Rev. 2006 Aug; 35(8):710-7.
Bulk characterization methods for non-centrosymmetric materials: second-harmonic generation, piezoelectricity, pyroelectricity, and ferroelectricity.
Synthesis, structure, and characterization of novel two- and three-dimensional vanadates: Ba2.5(VO2)3(SeO3)4.H2O and La(VO2)3(TeO6).3H2O. Inorg Chem. 2006 May 01; 45(9):3602-5.
Synthesis, structure, and characterization of novel two- and three-dimensional vanadates: Ba2.5(VO2)3(SeO3)4.H2O and La(VO2)3(TeO6).3H2O.
New metal iodates: syntheses, structures, and characterizations of noncentrosymmetric La(IO3)3 and NaYI4O12 and Centrosymmetric beta-Cs2I4O11 and Rb2I6O15(OH)2.H2O. Inorg Chem. 2005 Dec 12; 44(25):9353-9.
New metal iodates: syntheses, structures, and characterizations of noncentrosymmetric La(IO3)3 and NaYI4O12 and Centrosymmetric beta-Cs2I4O11 and Rb2I6O15(OH)2.H2O.
Mixed-metal tellurites: synthesis, structure, and characterization of Na1.4Nb3Te4.9O18 and NaNb3Te4O16. Inorg Chem. 2005 May 30; 44(11):3919-25.
Mixed-metal tellurites: synthesis, structure, and characterization of Na1.4Nb3Te4.9O18 and NaNb3Te4O16.
New d0 transition metal iodates: synthesis, structure, and characterization of BaTi(IO3)6, LaTiO(IO3)5, Ba2VO2(IO3)4.(IO3), K2MoO2(IO3)4, and BaMoO2(IO3)4.H2O. Inorg Chem. 2005 Apr 04; 44(7):2263-71.
New d0 transition metal iodates: synthesis, structure, and characterization of BaTi(IO3)6, LaTiO(IO3)5, Ba2VO2(IO3)4.(IO3), K2MoO2(IO3)4, and BaMoO2(IO3)4.H2O.
The lone-pair cation I(5+) in a hexagonal tungsten oxide-like framework: synthesis, structure, and second-harmonic generating properties of Cs(2)I(4)O(11). Angew Chem Int Ed Engl. 2004 Oct 18; 43(41):5489-91.
The lone-pair cation I(5+) in a hexagonal tungsten oxide-like framework: synthesis, structure, and second-harmonic generating properties of Cs(2)I(4)O(11).
Asymmetric cationic coordination environments in new oxide materials: synthesis and characterization of Pb(4)Te(6)M(10)O(41) (M = Nb(5+) or Ta(5+)). Inorg Chem. 2004 Jul 12; 43(14):4248-53.
Asymmetric cationic coordination environments in new oxide materials: synthesis and characterization of Pb(4)Te(6)M(10)O(41) (M = Nb(5+) or Ta(5+)).
Synthesis, structure, and characterization of two new layered mixed-metal phosphates, BaTeMO4(PO4) (M = Nb5+ or Ta5+. Inorg Chem. 2004 Feb 09; 43(3):964-8.
Synthesis, structure, and characterization of two new layered mixed-metal phosphates, BaTeMO4(PO4) (M = Nb5+ or Ta5+.
Combining second-order Jahn-Teller distorted cations to create highly efficient SHG materials: synthesis, characterization, and NLO properties of BaTeM2O9 (M = Mo6+ or W6+). J Am Chem Soc. 2003 Jul 02; 125(26):7764-5.
Combining second-order Jahn-Teller distorted cations to create highly efficient SHG materials: synthesis, characterization, and NLO properties of BaTeM2O9 (M = Mo6+ or W6+).
Syntheses, structures, and characterization of new lead(II)-tellurium(IV)-oxide halides: Pb3Te2O6X2 and Pb3TeO4X2 (X = Cl or Br). Inorg Chem. 2003 Jan 13; 42(1):205-9.
Syntheses, structures, and characterization of new lead(II)-tellurium(IV)-oxide halides: Pb3Te2O6X2 and Pb3TeO4X2 (X = Cl or Br).
Anionic templating: synthesis, structure, and characterization of novel three-dimensional mixed-metal oxychlorides Te(4)M(3)O(15).Cl (M = Nb(5+) or Ta(5+)). Inorg Chem. 2002 Jul 29; 41(15):3805-7.
Anionic templating: synthesis, structure, and characterization of novel three-dimensional mixed-metal oxychlorides Te(4)M(3)O(15).Cl (M = Nb(5+) or Ta(5+)).